2-(2,6-Di­chloro­phen­yl)-1-pentyl-4,5-diphenyl-1H-imidazole

The title compound, C₂₆H₂₄Cl₂N₂, crystallizes with two independent mol­ecules (1 and 2) in the asymmetric unit. In mol­ecule 1, the two phenyl and 2,6-di­chloro­phenyl rings are inclined to the imidazole ring at angles of 74.12 (14), 26.13 (14) and 67.30 (14)°, respectively. In mol­ecule 2, due to the different mol­ecular environment in the crystal, the corresponding angles are different, viz. 71.72 (15), 16.14 (15) and 80.41 (15)°, respectively. In the crystal, mol­ecules 1 and 2 are linked by C—H...Cl inter­actions, and inversion-related 2 mol­ecules are linked by C—H...π inter­actions. There are no other significant inter­molecular inter­actions present.

3-{[5-(4-Chloro­phen­yl)-3-methyl-1H-pyrazol-1-yl]meth­yl}-4-m-tolyl-1H-1,2,4-triazole-5(4H)-thione

In the title compound, C₂₀H₁₈ClN₅S, the toluene and triazole rings are oriented almost perpendicular to each other, making a dihedral angle of 89.97 (9)°, whereas the dihedral angle between cholorophenyl and pyrazole rings is 54.57 (11)°. In the crystal, pairs of N—H...N hydrogen bonds link the mol­ecules into inversion dimers. Weaker C—H...S and C—H...Cl inter­actions are also present.