organic compounds
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In the title squaraine dye solvate, C26H24N2O2·2CHCl3, the dye molecule is essentially planar, except for the methyl groups, having a maximum deviation over the 26-membered delocalized bond system of 0.060 (2) Å. It possesses crystallographic twofold rotational symmetry with the indole ring systems adopting a syn conformation. The molecular structure features intramolecular N—HO hydrogen bonds enclosing conjoint S7 ring motifs about one of the dioxocyclobutene O atoms, while the two chloroform solvent molecules are linked to the second O atom through C—HO hydrogen bonds.
organic compounds
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In the crystal of the title hydrated molecular salt, C8H12NO+·Cl−·H2O, the water molecule makes two O—HCl hydrogen bonds, generating [010] zigzag chains of alternating water molecules and chloride ions. The cation is bonded to the chain by an O—HO hydrogen bond and two weak C—HCl interactions. Weak aromatic π–π stacking [centroid–centroid separation = 3.5175 (15) Å] occurs between the chains.
organic compounds
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In the cation of the title salt, C8H11N2+·Br−, the dihedral angle between the planes of the pyridinium ring and the allyl group is 79.4 (3)°. In the crystal, N—HBr and weak C—HBr hydrogen bonds link the cations and anions, forming chains of alternating R21(7) and R42(8) rings, which run parallel to the c-axis direction. The crystal studied was an inversion twin with components in a 0.753 (12):0.247 (12) ratio.
organic compounds
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The title salt, C8H12NO+·Br−·H2O, is isomorphous with the chloride analogue [Seethalakshmi et al. (2013). Acta Cryst. E69, o835–o836]. In the solid state, the cations, anions and water molecules are interlinked by a network of O—HO, O—HBr and C—HBr interactions. The water molecule makes two O—HBr hydrogen bonds, generating [010] zigzag chains of alternating water molecules and bromide anions. The cation is involved in two intermolecular C—HCl interactions in the chloride salt, whereas three intermolecular C—HBr interactions are observed in the title bromide salt. This additional intermolecular C—HBr interaction links the adjacent water and bromide zigzag chains via cationic molecules. In addition, weak π–π stacking interactions are observed between pyridinium rings [centroid–centroid distance = 3.5664 (13) Å].