μ-Azido-κ²N¹:N¹-μ-chlorido-bis­[(2-chloro-3-dimethyl­amino-1-phenyl­prop-1-en-1-yl-κ²C¹,N)palladium(II)] chloro­form monosolvate

In the binuclear title complex, [Pd₂(C₁₁H₁₃ClN)₂Cl(N₃)]·CHCl₃, each Pd^II atom has a slightly distorted square-planar geometry being coordinated by a C and an N atom of the 2-chloro-3-dimethyl­amino-1-phenyl­propyl ligand, a bridging Cl atom and an N atom of a bridging end-on azide group. There is a short intra­molecular C—H...Cl contact in the complex mol­ecule. In the crystal, the chloro­form solvent mol­ecule is linked to the complex via a C—H...π inter­action.

(Benzyl isocyanide-κC¹)chlorido(2-chloro-3-dimethyl­amino-1-phenyl­prop-1-en-1-yl-κ²C¹,N)palladium(II)

In the title compound, [Pd(C₁₁H₁₃ClN)Cl(C₈H₇N)], which crystallized in the chiral space group P2₁2₁2₁, the Pd^II atom is coordinated by two C atoms, a Csp² atom of the 2-chloro-3-dimethyl­amino-1-phenyl­prop-1-en-1-yl ligand and a Csp atom from the benzyl isocyanide ligand, as well as an N atom of the ligand and a Cl atom, in a square-planar geometry. In the complex, there is a short C—H...Cl hydrogen bond and a C—H...π inter­action. In the crystal, mol­ecules are linked via C—H...Cl hydrogen bonds, forming chains along the a-axis direction.