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The whole mol­ecule of the title compound, C20H18N4O4, is generated by an inversion center. The benzimidazole ring mean plane make a dihedral angle of 89.4 (8)° with the plane passing through the acetate group (COO). In the crystal, mol­ecules are linked via weak C—H...O hydrogen bonds and π–π inter­actions [centroid–centroid distance = 3.743 (3) Å] involving inversion-related benzimidazole groups.
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