organic compounds
Open access
In the title compound, C10H9F2N3O, the dihedral angle between the mean planes of the triazole and benzene rings is 20.6 (2)°. In the crystal, molecules are linked by strong O—H N hydrogen bonds into chains with graph-set notation C(9) along [100]. Weak C—HN and C—HF interactions are also observed.
organic compounds
Open access
In the title compound, C13H13N3O, the NNCO unit forms dihedral angles of 35.8 (1) and 84.0 (1)° with the benzene and phenyl rings, respectively. The dihedral angles between the aromatic rings is 61.2 (1)°. An intramolecular N—HO hydrogen bond occurs. In the crystal, molecules are linked by weak N—HO hydrogen bonds into C(4) chains parallel to the c axis. Neighbouring chains are linked by weak N—HN hydrogen bonds, forming R44(20) rings, and resulting in the formation of a two-dimensional network lying parallel to (010). The packing also features π–π stacking interactions between phenyl rings [centroid–centroid distance = 3.803 (2) Å].
organic compounds
Open access
In the title compound, C20H18BrN5, the bromophenyl-substituted quinazoline unit is essentially planar [maximum deviation = 0.098 (3) Å] and makes a dihedral angle of 56.04 (14)° with the imidazole ring. In the crystal, molecules are associated by pairs of N—HN hydrogen bonds to form inversion dimers. All the quinazoline planar systems are oriented almost perpendicular to the [110] direction, making π–π interactions possible between adjacent dimers [centroid–centroid distances = 3.7674 (16) and 3.7612 (17) Å]. There are also a number of C—Hπ interactions present. The crystal is a nonmerohedral twin, with a minor twin fraction of 0.47.