organic compounds
Open access
The title compound, C12H13ClN2O2, crystallizes with two independent but very similar molecules (A and B) in the asymmetric unit. The pyrazole ring in each molecule has an envelope conformation. The dihedral angle between the pyrazole ring mean plane and the benzene ring is 86.07 (14)° in A and 85.99 (14)° in B. In the crystal, the A and B molecules are linked via a pair of O—HO hydrogen bonds, forming dimers. These dimers are further linked via C—HO interactions to form –A–B–A–B– chains propagating along the c-axis direction.
organic compounds
Open access
In the title compound, C13H12O2, the dihedral angle between the pyranone and phenyl rings is 57.55 (9)°. In the crystal, the molecules are linked by π–π stacking interactions between the parallel pyranone rings of neighboring molecules with distances of 3.5778 (11) Å and 3.3871 (11) Å between the planes. C—HO interactions also occur.