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Tb2Ni2Mg3 is a new structure type, derived from Ru3Al2B2, which can be viewed as the first representative of a homologous linear structure series based on the [alpha]-Fe, CsCl and AlB2 structure types. The Tb atoms in the structure are enclosed in 17-vertex polyhedra, while rhombododeca­hedra and distorted rhombododeca­hedra surround the Mg atoms, and equatorially tricapped trigonal prisms form around the Ni atoms.
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