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The title compound (H2DTMSP[EBP]), C14H36O6P2Si2, was crystallized by the slow evaporation of a solution in a 20:1 mixture of pentane and acetone. The H2DTMSP[EBP] mole­cule lies about an inversion center. In the solid state, the mol­ecule exists in an anti configuration, with the mol­ecular backbone C-C bond located on an inversion center. The compound exists in the solid state as hydrogen-bonded infinite sheets in the ab plane, unlike the methyl­ene analogue, which exists as hydrogen-bonded infinite chains, demonstrating an `even-odd' effect of the length of the backbone alkyl chain.
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