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In three differently solvated Cu2+ complexes of 1,3-bis­(penta­fluoro­phen­yl)propane-1,3-dionate, the p-xylene solvent mol­ecules are involved in arene-perfluoro­arene inter­actions with the penta­fluoro­phenyl groups. In a tetra­solvate, two of the p-xylene mol­ecules are located on the coordination CuO4 plane forming a uniform cavity produced by metal...[pi] inter­actions.
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