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The absolute configuration of the enantio­pure anti-head-to-head cyclo­dimer of anthracene-2-carb­oxy­lic acid was determined. The dimer inter­acts with L-prolinol through a nine-membered hydrogen-bonded ring [R_{2}^{2}(9)], while a di­chloro­methane mol­ecule is incorporated to fill the void space.
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