(Hexafluorosilicato-²F,F')bis(1,10-phenanthroline-²N,N')zinc(II) methanol monosolvate

R. W. Seidel, C. Dietz, J. Breidung, R. Goddard and I. M. Oppel

The title compound contains a neutral heteroleptic tris-chelate Zn^II complex, viz. [Zn(SiF₆)(phen)₂] (phen is 1,10-phenanthroline), exhibiting approximate molecular C₂ point-group symmetry, and represents the first structurally characterized example of a Zn^II complex bearing a bidentate-bound hexafluorosilicate ligand.

Keywords: crystal structure; zinc complex; coordination compound; hexafluorosilicate ligand; density functional theory (DFT) calculations.

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(Hexa­fluoro­silicato-2F,F')bis­(1,10-phenanthroline-2N,N')zinc(II) methanol monosolvate

(Hexafluorosilicato-²F,F')bis(1,10-phenanthroline-²N,N')zinc(II) methanol monosolvate