organic compounds
The title compound, C16H9FN2S, crystallizes as a nonmerohedral twin with twin rotation about the reciprocal-lattice vector [10]*. The molecules are nearly planar and the dihedral angle between the planes of the two aryl rings is only 4.4 (2)°. The molecules are linked by pairs of C-HN hydrogen bonds to form cyclic centrosymmetric R22(18) dimers, which are linked into chains by an aromatic - stacking interaction. Comparisons are made with some related 3-aryl-2-thienylacrylonitriles.
organic compounds
The central C-C-C angle is 120.3 (2)° and the molecules are linked by N-HO hydrogen bonds into a ribbon containing edge-fused S(8) and (8) rings.