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The title compound, [K(C14H23)(C4H8O)]n, comprises zigzag chains of alternating bridging 2,3,4,5-tetra­methyl-1-n-pentyl­cyclo­penta­dienyl ligands and potassium ions, with an ancillary tetra­hydro­furan ligand in the coordination environment of potassium. The coordination polymer strands so formed extend by 21 screw symmetry in the b-axis direction. The chemically modified cyclo­penta­dienyl ligand, with a tethered n-pentyl group, was synthesized from 2,3,4,5-tetra­methyl­cyclo­pent-2-enone by a Grignard reaction.
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