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A novel supra­molecular framework, catena-poly[[[aqua(2-phenyl­quinoline-4-carboxyl­ato-[kappa]O)silver(I)]-[mu]-4,4'-bipyridine-[kappa]2N:N'] dihydrate], {[Ag(C16H10NO2)(C10H8N2)(H2O)]·2H2O}n, has been synthesized and structurally characterized. The AgI centres are four-coordinated and bridged by 4,4'-bi­pyridine (4,4'-bipy) ligands to form a one-dimensional Ag-bipy chain. The Ag-bipy chains are further linked together by inter­molecular O-H...O and O-H...N hydrogen-bonding inter­actions between adjacent chains, resulting in a three-dimensional framework.
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