metal-organic compounds
In the crystal structure of the title complex, [Ni2(C10H20N4O2)(C12H12N2)2](ClO4)2 or [Ni(dmaeoxd)Ni(dmbp)2](ClO4)2 {H2dmaeoxd is N,N'-bis[2-(dimethylamino)ethyl]oxamide and dmbp is 4,4'-dimethyl-2,2'-bipyridine}, the deprotonated dmaeoxd2- ligand is in a cis conformation and bridges two NiII atoms, one of which is located in a slightly distorted square-planar environment, while the other is in an irregular octahedral environment. The cation is located on a twofold symmetry axis running through both Ni atoms. The dmaeoxd2- ligands interact with each other via C-HO hydrogen bonds and - interactions, which results in an extended chain along the c axis.