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In the title compound, [Ge(C8H14NO)2Cl]CF3SO3, which is the first complex containing an eight-membered lactam (enantho­lactam) as ligand, the coordination polyhedron of the GeIV atom is inter­mediate between trigonal-bipyramidal and square-pyramidal. Quantum chemical calculations of the crystal structure indicate the absence of additional coordination bonding between the GeIV atom and the trifluoro­methane­sulfonate anion.
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