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metal-organic compounds
The title dinuclear di-![[mu]](/logos/entities/mu_rmgif.gif)
-oxo-bis[(1,4,8,11-tetraazacyclotetradecane-![[kappa]](/logos/entities/kappa_rmgif.gif)
4N)manganese(III,IV)] diperchlorate nitrate complex, [Mn2O2(C10H24N4)2](ClO4)2(NO3) or [(cyclam)MnO]2(ClO4)2(NO3), was self-assembled by the reaction of Mn2+ with 1,4,8,11-tetraazacyclotetradecane in aqueous media. The structure of this compound consists of a centrosymmetric binuclear [(cyclam)MnO]3+ unit, two perchlorate anions and one nitrate anion. While the low-temperature electron paramagnetic resonance spectra show a typical 16-line signal for a di--oxo MnIII/MnIV dimer, the magnetic susceptibility studies also confirm a characteristic antiferromagnetic coupling between the electronic spins of the MnIV and MnIII ions.
-oxo-bis[(1,4,8,11-tetraazacyclotetradecane-4N)manganese(III,IV)] diperchlorate nitrate complex, [Mn2O2(C10H24N4)2](ClO4)2(NO3) or [(cyclam)MnO]2(ClO4)2(NO3), was self-assembled by the reaction of Mn2+ with 1,4,8,11-tetraazacyclotetradecane in aqueous media. The structure of this compound consists of a centrosymmetric binuclear [(cyclam)MnO]3+ unit, two perchlorate anions and one nitrate anion. While the low-temperature electron paramagnetic resonance spectra show a typical 16-line signal for a di--oxo MnIII/MnIV dimer, the magnetic susceptibility studies also confirm a characteristic antiferromagnetic coupling between the electronic spins of the MnIV and MnIII ions.
