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In the title complex, {[Cu(C12H10N2)2]BF4}n, each copper(I) centre is tetra­hedrally coordinated by N atoms from four bridging trans-1-(2-pyrid­yl)-2-(4-pyrid­yl)ethyl­ene (TPPE) ligands. The ligands bridge adjacent copper(I) centres to form one-dimensional folded chains. Adjacent uniform chains are further inter­linked into a three-dimensional framework through weak C—H...F inter­actions.
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