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The title organic salt, 2C10H9N2+·C10H4O82-·C10H6O8 or 2(H-2,4'bpy)(H2bta)·H4bta (where H-2,4'bpy is the 2,4'-bipyridine cation, H2bta is the 2,5-dicarboxy­benzene-1,4-carboxyl­ate anion and H4bta is the benzene-1,2,4,5-tetra­carboxylic acid mol­ecule), crystallizes with both the H2bta dianion and the H4bta mol­ecule lying about inversion centres in the triclinic unit cell. This organic salt is formed by an extensive and complex hydrogen-bonding network containing both homo- and heteronuclear neutral and ionic inter­actions.
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