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The title compound, C15H12NO2F3, adopts the phenol–imine tautomeric form. The two aromatic rings are twisted with respect to each other, with a dihedral angle of 17.83 (19)°. O—H...N and O—H...F intra­molecular inter­actions are found in the mol­ecule, and the solid-state structure is stabilized by inter­molecular C—H...O and C—H...F hydrogen bonds, to form a two-dimensional network.

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The title compound, C20H25N3O5, adopts the keto–amine tautomeric form and displays the characteristic features of azobenzene derivatives. Intra­molecular N—H...O and O—H...O and inter­molecular O—H...O inter­actions influence the conformation of the mol­ecules and the crystal packing.
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