organic compounds
The title compound, C17H16O5, crystallizes with two independent molecules in the asymmetric unit. These are oriented approximately orthogonal to one another. The keto group adopts an s-cis conformation; the six-membered ring formed by the O—HO hydrogen bond and the adjacent benzene ring are approximately coplanar. In addition to an intramolecular O—HO hydrogen bond, intermolecular O—HO interactions link adjacent molecules into chains.
organic compounds
In the title compound, C18H11Cl2O3PS, the seven-membered phosphepine ring exhibits a distorted-boat conformation, with the phosphoryl sulfide group axial and the dichlorophenoxy group equatorial. Fusion of the phosphepine ring to the biphenyl system causes strain, as evidenced by both widening and compression of the endocyclic angles in the heterocyclic ring. The P=S bond length is 1.8939 (12) Å and the planar dichlorophenyl ring is oriented at an angle of 28.70 (6)° to the phosphepine ring.
organic compounds
Molecules of the title compound, C18H16O6, are almost planar. The dihedral angle between the benzopyran system and the benzene ring is 3.36 (5)°. In addition to an intramolecular O—HO hydrogen bond, molecules are connected by weak intermolecular C—HO hydrogen bonds to form a two-dimensional framework.
organic compounds
The γ-pyranone ring of the title molecule, C16H14O5, adopts an envelope conformation. The crystal packing is stabilized by O—HO and C—HO hydrogen bonding.