Crystal structure of [3-(4,5-di­hydro-1,3-thia­zolin-2-yl-κN)-1,3-thia­zolidine-2-thione-κS²](1,3-thia­zol­idine-2-thione-κS²)copper(I) nitrate

In the mononuclear complex title salt, all of the non-H atoms of the cation lie on a mirror plane, as do the N and one O atom of the nitrate anion, such that the planes of the cation and anion are mutually orthogonal. In the crystal, layers parallel to (010) are generated by N—H...O hydrogen bonds, supported by short S...O [3.196 (4) and 3.038 (3) Å] and S...S contacts [3.4392 (13) Å].

(N-Phenyl­thio­urea-κS)bis­(tri­phenylphosphane-κP)silver(I) nitrate

In the title salt, [Ag(C₇H₈N₂S)(C₁₈H₁₅P)₂]NO₃, the coordination geometry about the Ag^I atom is shallow trigonal pyramidal, with the metal atom displaced by 0.372 (1) Å from the plane of the P and S atoms. In the crystal, the cations are linked to the anions by N—H...O hydrogen bonds, generating tetra­mers (two cations and two anions), which feature R₂²(8) and R₄⁴(8) loops. The cations are linked by weak C—H...π inter­actions, generating a three-dimensional network.