Iodido­bis­(morpholine-4-carbodi­thio­ato-κ²S,S′)(1,10-phenanthroline-κ²N,N′)bis­muth(III)

The title compound, [Bi(C₄H₈NOS₂)₂I(C₁₂H₈N₂)], is monomeric, with the Bi^III atom chelated by the two S atoms of two morpholine-4-carbodi­thio­ate ligands and the two N atoms of a 1,10-phenanthroline ligand. An iodide ligand completes the coordination sphere, with the seven-coordinate Bi^III atom adopting a highly distorted monocapped octa­hedral geometry.

1,3,5-Tris(4-meth­oxy­phen­yl)-1,3,5-triazinane-2,4,6-trione

The complete mol­ecule of the title compound, C₂₄H₂₁N₃O₆, is generated by the application of threefold rotation symmetry about an axis perpendicular to the central ring. The mol­ecule exhibits a propeller-like shape. The dihedral angle between each benzene ring and the heterocyclic ring is 74.0 (1)°. The mol­ecules pack with no specific inter­molecular inter­actions between them. The SQUEEZE procedure in PLATON [Spek (2009). Acta Cryst. D65, 148-155] was used to model disordered solvent mol­ecules, presumed to be acetone; the calculated unit-cell data do not take into account the presence of these.

(R)-[(R)-3-Benzyl-2-oxooxazolidin-4-yl][4-(methyl­sulfon­yl)phen­yl]methyl acetate

The structure of the title compound, C₂₀H₂₁NO₆S, is of inter­est with respect to its anti­bacterial properties. The oxazolidine ring makes dihedral angles of 79.63 (14) and 56.16 (12)° with the phenyl and benzene rings, respectively, while the phenyl and benzene rings make a dihedral angle of 64.37 (13)°. In the crystal, non-classical C—H...O hydrogen bonds link adjacent mol­ecules along the c axis.