Bis[μ-N-(pyridin-2-ylmeth­yl)pyridin-3-amine-κ²N:N′]disilver(I) bis­(perchlorate) dimethyl sulfoxide disolvate

In the binuclear title compound, [Ag₂(C₁₁H₁₁N₃)₂](ClO₄)₂·2C₂H₆SO, the complex cation is centrosymmetric, with the unique Ag^I cation coordinated by two pyridine N atoms from two symmetry-related N-(pyridine-2-ylmeth­yl)pyridine-3-amine ligands in a geometry slightly distorted from linear [N—Ag—N = 170.78 (9)°], resulting in the formation of a 16-membered cyclic dimer. The two pyridine rings coordinating to the Ag^I atom are almost perpendicular to each other [dihedral angle = 87.73 (10)°]. Inter­molecular Ag...O inter­actions [3.149 (3) and 2.686 (3) Å], N—H...O and C—H...O hydrogen bonds and C—H...π inter­actions between the cyclic dimers and the anions or the solvent mol­ecules lead to the formation of a three-dimensional supra­molecular network.