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In the title mol­ecule, C20H18N2O3, the pyrazole ring forms a dihedral angle of 2.2 (1)° with its meth­oxy­phenyl substituent and a dihedral angle of 67.2 (1)° with the benzene substituent on the propenal unit. In the crystal, mol­ecules are connected by weak C—H...O hydrogen bonds, forming R22(26) and R22(28) cyclic dimers that lie about crystallographic inversion centres. These dimers are further linked through C—H...O and C—H...N hydrogen bonds, forming C(8), C(9), C(10) and C(16) chain motifs. These primary motifs are further linked to form secondary C22(15) chains and R22(18) rings.

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In the title salt, 2C6H9N2O2S+·SO42−, the sulfate S atom is situated on a crystallographic twofold axis (the symmetry of the anion is 2). The anion exerts intense libration, which is manifested by shortening of the observed sulfate S—O bonds, as well as by features in the electron-density map. The crystal structure is stabilized through a three-dimensional hydrogen-bonding network formed by strong N—H...O hydrogen bonds.
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