metal-organic compounds
Open access
The SbV atom in the title compound, [SbCl2(C6H4Br)3], has an almost regular trigonal–bipyramidal geometry with the equatorial plane made up of three C atoms of the bromophenyl groups and the axial positions occupied by two Cl− ions in a trans configuration. In the crystal, C—HBr hydrogen bonds link the molecules into zigzag chains along the b-axis direction. Pairs of C—HCl hydrogen bonds further link molecules into cyclic dimers with R22(10) ring motifs, generating a three-dimensional network.
organic compounds
Open access
In the title compound, C10H8ClNOSe, the dihedral angle between benzene and selenazole rings is 11.4 (3)° and the hydroxymethyl group is bent from the selenazole ring, making a dihedral angle of 63.8 (3)°. In the crystal, molecules are linked into inversion dimers by pairs of O—HN hydrogen bonds. Roof-tile-like stacking of the molecules along [010] [b = 4.5707 (4) Å] is observed, with the benzene and selenazole rings separated by a face-to-face distance of 3.57 Å and a mutual slippage of 2.85 Å.