metal-organic compounds
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The SbV atom in the title compound, [SbCl2(C6H4Br)3], has an almost regular trigonal–bipyramidal geometry with the equatorial plane made up of three C atoms of the bromophenyl groups and the axial positions occupied by two Cl− ions in a trans configuration. In the crystal, C—HBr hydrogen bonds link the molecules into zigzag chains along the b-axis direction. Pairs of C—HCl hydrogen bonds further link molecules into cyclic dimers with R22(10) ring motifs, generating a three-dimensional network.