metal-organic compounds
Open access
In the title compound, [AgCl(C24H24N2)], the terminal phenyl and tetramethylbenzene rings [which form a dihedral angle of 87.92 (14)°] make dihedral angles of 59.59 (11) and 83.19 (12)° with respect to the central benzimidazole ring system. The Ag—C and Ag—Cl single-bond lengths are 2.087 (3) and 2.3267 (9) Å. The C—Ag—Cl bond angle is 172.84 (7)°. C—Hπ interactions contribute to the stabilization of the crystal structure. A very weak π–π stacking interaction between adjacent tetramethylbenzene rings [centroid–centroid distance = 4.0610 (18) Å] is also observed.
organic compounds
Open access
In the title compound, C18H21NO4S, the aromatic rings are almost normal to each other, with a dihedral angle of 89.27 (18)°. The molecular conformation is stabilized by an intramolecular C—HO interaction, which generates an S(6) motif. In the crystal, N—HO and C—HO hydrogen bonds lead to the formation of chains propagating along [010]. Neighbouring chains are linked via a C—Hπ interaction. The –CH2CH2CH3 atoms of the butyl group are disordered over two sets of sites, with a refined site-occupancy ratio of 0.536 (16):0.464 (16).
organic compounds
Open access
In the title compound, C16H22ClNS, the nine-membered 2,3-dihydro-1,3-benzothiazole ring system is essentially planar, with a maximum deviation of 0.025 (2) Å for the N atom. Its plane is almost perpendicular to the main plane of the substituted cyclohexane ring, which adopts a chair conformation. In the crystal, the molecules are linked by C—Hπ interactions.