metal-organic compounds
Open access
The title compound, [Cu(C2Cl3O2)2(C3H4N2)4], was prepared by the reaction of imidazole and trichloroacetatocopper(II). The CuII atom adopts a distorted octahedral coordination geometry, binding the N atoms of four imidazole ligands and the carboxylate O atoms of two trichloroacetate anions. The molecular structure and packing are stabilized by N—HO hydrogen-bonding interactions. Close intermolecular ClCl contacts [3.498 (3) Å] are also found in the structure.
organic compounds
Open access
In the title compound, C15H15NO4, the quinoline ring system and one of the malonate side chains are essentially coplanar (r.m.s. deviation = 0.0297 Å). The two malonate C—C(=O)—O—CH3 side chains are oriented at right angles [89.68 (8)°] with respect to each other. The crystal packing is stabilized by weak non-classical intermolecular C—HO hydrogen bonds, which link the molecules into dimers about inversion centers.