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The title compound, [Cu(C2Cl3O2)2(C3H4N2)4], was prepared by the reaction of imidazole and trichloro­acetatocopper(II). The CuII atom adopts a distorted octa­hedral coordination geometry, binding the N atoms of four imidazole ligands and the carboxyl­ate O atoms of two trichloro­acetate anions. The mol­ecular structure and packing are stabilized by N—H...O hydrogen-bonding inter­actions. Close inter­molecular Cl...Cl contacts [3.498 (3) Å] are also found in the structure.

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In the title compound, C15H15NO4, the quinoline ring system and one of the malonate side chains are essentially coplanar (r.m.s. deviation = 0.0297 Å). The two malonate C—C(=O)—O—CH3 side chains are oriented at right angles [89.68 (8)°] with respect to each other. The crystal packing is stabilized by weak non-classical inter­molecular C—H...O hydrogen bonds, which link the mol­ecules into dimers about inversion centers.
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