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In the title compound, C20H22N2O3·0.25H2O, the water mol­ecule (occupancy 0.25) is disordered across a crystallographic inversion center. The dihedral angle between the hydroxy­phenyl ring and the benzimidazole ring system is 59.31 (9)°. In the crystal structure, mol­ecules are connected by inter­molecular O—H...N and C—H...O hydrogen bonds. The crystal structure is further stabilized by a weak C—H...π inter­action involving the imidazole ring.

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In the title compound, C32H30N2O7, the piperidone ring adopts a chair conformation and the five-membered ring of the dihydro­indenone ring system adopts an envelope conformation. Intra­molecular O—H...N and C—H...O hydrogen bonds occur. The dihedral angle between the two hydr­oxy-subsituted methoxy­phenyl rings is 71.12 (5)°. In the crystal structure, mol­ecules are connected by inter­molecular O—H...O hydrogen bonds, forming layers parallel to (001). These layers are further connected by C—H...O hydrogen bonds, forming a three-dimensional network.

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In the title compound, C32H26Cl2N2O3, the piperidone ring adopts a chair conformation and the proline and pyrrolidine rings adopt envelope conformations. The indane ring system is essentially planar with an r.m.s. deviation of 0.011 Å for the non-H atoms. The dihedral angle between the two chloro-substituted benzene rings is 63.69 (10)°. Intra­molecular C—H...O and N—H...O hydrogen bonds may influence the mol­ecular conformation. In the crystal structure, mol­ecules are connected into layers by weak inter­molecular C—H...O hydrogen bonds.

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In the title compound, C19H12FN3O2S, the chromene ring system and the thia­zole ring are approximately planar [maximum deviations of 0.023 (3) Å and 0.004 (2) Å, respectively]. The chromene ring system is inclined at angles of 4.78 (10) and 26.51 (10)° with respect to the thia­zole and benzene rings, respectively, while the thia­zole ring makes a dihedral angle of 23.07 (12)° with the benzene ring. The mol­ecular structure is stabilized by an intra­molecular C—H...O hydrogen bond, which generates an S(6) ring motif. The crystal packing is consolidated by inter­molecular N—H...O hydrogen bonds, which link the mol­ecules into chains parallel to [100], and by C—H...π and π–π [centroid–centroid distance = 3.4954 (15) Å] stacking inter­actions.

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The title compound, C12H10BrN3O2S, exists in an E configuration with respect to the C=N bond. The approximately planar 2H-chromene ring system [maximum deviation = 0.059 (1) Å] is inclined at a dihedral angle of 17.50 (5)° with respect to the mean plane through the thio­semicarbazide unit and an intra­molecular N—H...N hydrogen bond generates an S(5) ring. In the crystal structure, adjacent mol­ecules are linked by N—H...S hydrogen bonds, forming [010] chains built up from R22(8) loops, such that each S atom accepts two such bonds. These chains are further inter­connected into sheets parallel to the ab plane via short Br...O inter­actions [3.0732 (13) Å] and a π–π aromatic stacking inter­action [3.7870 (8) Å] is also observed.

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In the title compound, C19H13N3O3S·0.5H2O, both organic mol­ecules (A and B) exist in E configurations with respect to the acyclic C=N bond and have similar overall conformations. In mol­ecule A, the essentially planar thia­zole ring [maximum deviation = 0.010 (2) Å] is inclined at inter­planar angles of 11.44 (10) and 32.50 (12)°, with the 2H-chromene ring system and the benzene ring, respectively. The equivalent values for mol­ecule B are 0.002 (2) Å, 7.71 (9) and 12.51 (12)°. In the crystal structure, neighbouring mol­ecules are inter­connected into infinite layers lying parallel to (010) by O—H...O, O—H...N, N—H...O and C—H...O hydrogen bonds. Further stabilization of the crystal structure is provided by weak inter­molecular C—H...π and π–π [centroid–centroid distance = 3.6380 (19) Å] inter­actions.
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