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In the title complex, [La(NO3)2(bib)2(H2O)2]·0.5bib·H2O [bib is 1,4-bis­(1-imidazol­yl)benzene, C12H10N4], the LaIII atom is coordinated by two N atoms from two bib ligands and eight O atoms from three nitrate and two water ligands. This mononuclear complex is further extended into a three-dimensional structure via hydrogen bonds with free bib and water mol­ecules of crystallization, the former lying on inversion centers.
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