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The FeIIIS2N2O2 chromophore contains two O,N,S-donating dianionic 3-ethoxysalicylaldehyde 4-methyl­thiosemicarbazonate(2-) ligands in perpendicular planes, with the O and S atoms in cis positions and the N atoms in trans positions. The FeIII cation is in the low-spin state at 100 K.
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