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N-(3,4,5-Tri­meth­oxy­benzyl­idene)naphthalen-1-amine forms simple hydrogen-bonded sheets built from C-H...O hydrogen bonds, linked by [pi]-[pi] stacking inter­actions, and its reduction product forms complex sheets built from N-H...O, C-H...O and C-H...[pi](arene) hydrogen bonds.
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