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For the new organic salt 1H-imidazol-3-ium 1,4-dioxo-1,4-dihydro­naphthalen-2-olate, C3H5N2+·C10H5O3-, ab initio cal­cul­ations of the gas-phase structures of the lawsonate and imidazolium ions were performed to help in the inter­pretation of the structural features observed. Three different types of hydrogen bond are responsible for the three-dimensional packing of the salt.
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