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The title compound, [CuMo4O13(C21H15N3)2]n, was synthesized by the reaction of ammonium molybdate, copper acetate and 4-[3,5-bis­(pyridin-4-yl)phen­yl]pyridine (DPPP) in an aqueous medium under hydro­thermal conditions. The two unique molybdenum centers and the copper center adopt MoO4 tetra­hedral, MoO5N octa­hedral and CuO4N2 octa­hedral geometries, respectively. These polyhedra are connected to each other through corner-sharing to form a two-dimensional Cu–Mo–O layer, which is further linked by the DPPP ligands to form the three-dimensional inorganic–organic hybrid framework.
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