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The mol­ecule of the title compound, tetra-[mu]2-acetato-diaquadi-[mu]2-chloro-tetra­chloro­tetra­kis[[mu]4-3-hydroxy-2,2-bis­(oxido­meth­yl)propanol­ato]­tetra­methanoldi-[mu]3-methanolato-di-[mu]5-oxo-octa­manganese(II)­tetra­manganese(III), [Mn4IIIMn8II(CH3O)2(C2H3O2)4(C5H9O4)4Cl6O2(CH4O)4(H2O)2], displays a centre of symmetry. The structure of the {Mn4IIIMn8IIO18Cl2}10- core is composed of three layers and features two oxo ligands binding in a rare [mu]5-mode.
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