metal-organic compounds
The title compound, [Ni(C3H4N2)5(H2O)](C4H2Br2O4), consists of NiII complex cations and dibromosuccinate anions. The Ni atom, water O atom and one imidazole N atom of the complex cation lie on a twofold axis. The anion lies on an inversion centre. The crystal packing is reinforced by O—HO and N—HO hydrogen bonds, but there are no π–π stacking interactions even though the complex contains five aromatic imidazole rings. The compound is isostructural with its cobalt analogue.