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The title compound, C32H24Cl2O2·C3H6O, was synthesized by the dimerization of 2-(4-chloro­benzal)inden-1-one, induced by a low-valent titanium reagent (TiCl4/Zn). X-ray analysis reveals that the cyclo­pentane ring spiro-fused to the five-membered ring adopts an envelope conformation, while the other cyclo­pentane ring adopts an envelope conformation.

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The title compound, C32H24Cl4O2·C3H6O, was obtained as a by-product of the reaction of 2-(2',4'-dichloro­benzal)-1-inden-1-one induced by a low-valent titanium reagent (TiCl4/Zn). Each of the fused cyclo­pentane rings adopts an envelope conformation.
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