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The title structure, {[Ag(C8H10N4)]NO3·1.167H2O·0.33CH4O}n, consists of helical chains in which approximately linearly coordinated Ag atoms alternate with bridging 1,1′-dimethyl-2,2′-biimidazole ligands in a syn conformation. The environment of each Ag atom is completed by weak Ag—O bonds to a bidentate nitrate ion.
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