journal menu
organic compounds
The title compound, C24H20N2O3S, crystallizes with two independent molecules in the asymmetric unit, related by a non-crystallographic twofold rotation axis. The two molecules differ in the relative orientations of the phenylsulfonyl group and the indole ring system. In both molecules, the seven-membered ring adopts a distorted boat conformation. The molecular packing is stabilized by C—H
π and C—HO interactions.
π and C—HO interactions.organic compounds
In the title compound, C23H19Br2NO4S, the orientation of the phenylsulfonyl substituent with respect to the indole ring system is influenced by intramolecular C—HO interactions. The sulfonyl-bound phenyl ring is orthogonal to the indole ring system. In the crystal structure, π–π stacking interactions involving the indole ring system link symmetry-related molecules into dimers.
O interactions. The sulfonyl-bound phenyl ring is orthogonal to the indole ring system. In the crystal structure, π–π stacking interactions involving the indole ring system link symmetry-related molecules into dimers.
