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In the structure of the title complex, [Cu(C14H9N3O4)(C4H9NO)], the Cu atom is coordinated by two O atoms and one N atom from the N-salicylaldehyde p-nitro­benzoyl­hydrazone ligand and one N atom from a morpholine mol­ecule, forming a square-planar Cu(ONO)(N) coordination. The g factors derived by an electron paramagnetic resonance study are typical for square-planar complexes.

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The CoIII atom in the title complex, [Co(C2H3O2)(C4H9NO)2(C15H11N3O5)], is coordinated by phenol O, carbonyl O and hydrazine N atoms of the N-salicylaldehyde-N′-(o-nitro­phenoxyac­yl)hydrazone ligand, L2−, one acet­oxy O atom, and two N atoms of two coordinated morpholine mol­ecules, forming an elongated octa­hedron. There is an inter­molecular N—H...O hydrogen bond between two morpholine mol­ecules from two neighbouring complex mol­ecules, generating an extended chain structure.
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