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In the title co-crystal, C10H11NO2·C10H13NO2, the carboxyl­ic acid moiety uses its acid H atom as the donor atom to bind strongly to the negatively charged O atom of the zwitterionic moiety [O...O = 2.557 (2) Å]. Meanwhile, the protonated N atom of the zwitterionic moiety forms a hydrogen bond with the double-bonded O atom of an adjacent zwitterionic moiety [N...O = 2.703 (2) Å] to give rise to a linear chain motif. The butenyl substituent (on the zwitterion) is disordered with respect to a butyl group and the butyl substituent (on the neutral mol­ecule) is disordered with respect to a butenyl group, the site occupancy for both being in an approximate 0.6:0.4 ratio.
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