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In the title compound, C18H14BrN3O2S, the three rings are nearly coplanar. In the crystal structure, intermolecular N—H...N and C—H...O hydrogen-bond interactions link the mol­ecules into ribbons, displaying alternate rings of graph-set motifs R22(8) and R22(14).

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The title compound, C18H13F3N4O2S, forms stacks via a three-dimensional hydrogen-bonding network, which involves intramolecular N—H...O, intermolecular C—H...O and paired N—H...O hydrogen bonds.

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The title compound, C18H27N3O3S, is an organocatalyst prepared from (1R,2R)-cyclo­hexa­ne-1,2-diamine. There are bifurcated N—H...N/O intra­molecular hydrogen bonds and N—H...O and C—H...O inter­molecular inter­actions.
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