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The title compound, C15H13N3S, was prepared by the reaction of 1-(2-chloro­ethyl)­benzene with hydrazine and phenyl iso­thio­cyanate. Packing is stabilized by N—H...S intermolecular hydrogen bonds and C—H...π interactions.

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The title compound, C15H15N3S, was prepared by the reaction of acetophenone and hydrazine with phenyl­isothio­cyanate. In the mol­ecule, all bond lengths and angles are within normal ranges. The two phen­yl rings make a dihedral angle of 61.6 (2)°. The crystal packing is stabilized by van der Waals forces.

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In the title compound, [CuCl2(C6H5Cl2N)2], each Cu atom has a distorted tetra­hedral coordination involving two Cl anions and two 2-chloro-5-(chloro­meth­yl)pyridine ligands. The mol­ecular structure and packing are stabilized by intra- and intermolecular C—H...Cl hydrogen-bonding inter­actions.
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