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The title compound, {[Cd3(C9H3O6)2(H2O)2]·2H2O}n, consists of a three-dimensional channel-like network. The asymmetric unit contains two crystallographically independent CdII ions, one of which shows a distorted trigonal prismatic coordination provided by six O atoms from one bidentate and three monodentate carboxyl­ate groups, and one water mol­ecule. The second independent CdII ion, which lies on an inversion centre, displays a distorted octahedral coordination environment provided by six O atoms from four monodentate carboxyl­ate groups and two water mol­ecules.

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The title compound, C11H10N4OS2, has a twofold axis passing through the carbonyl group. The mol­ecules stack along the b axis via π–π interactions.
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