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The title compound, [Cd2Cl4(C18H14N4O)2], was obtained from the reaction of Cd(NO3)2·4H2O with 2-phenyl­pyridine­keton picolinoyl hydrazone and sodium chloride. Each Cd2+ cation is coordinated by two N atoms and one O atom of the tridentate ligand and three chloride anions, forming a distorted CdNOCl3 octahedron. Each pair of adjacent metal cations is linked by two bridging chloride ligands, resulting in a dinuclear complex unit. The mol­ecular conformation is stabilized by intra­molecular N—H...N and C—H...O hydrogen bonds. In the crystal, mol­ecules are linked by nonclassical C—H...O and C—H...Cl hydrogen bonds into a three-dimensional network. In addition, π–π stacking inter­actions [centroid–centroid distances = 3.777 (2) and 3.631 (2) Å] contribute to the stabilization of the crystal packing.
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