organic compounds
Open access
The title compound, C18H30N2O5S, was synthesized by the reaction of tert-butyl 2-(isobutylamino)ethylcarbamate with p-methoxyphenylsulfonyl chloride. In the molecule, two intramolecular C—HO hydrogen bonds are observed. In the crystal, molecules are linked by N—HO hydrogen bonds involving the imino group N atom and the ester group O atom into chains running parallel to the b axis. The chains are further connected by C—HO hydrogen bonds, forming layers parallel to the bc plane.
organic compounds
Open access
The asymmetric unit of the title compound, C8H9N5O2, contains two independent molecules (A and B) in which the dihedral angles between the triazole and pyrazole rings are 4.80 (14) and 8.45 (16)°. In the crystal, molecules are linked by N—HN hydrogen bonds into supramolecular independent A and B chains propagating along the b-axis direction. The crystal structure also features π–π stacking between the aromatic rings of adjacent chains, the centroid–centroid separations being 3.8001 (15), 3.8078 (17), 3.8190 (14) and 3.8421 (15) Å.
organic compounds
Open access
The title compound, C14H28N2O5S, was synthesized by the reaction of 2-[(methylsulfanyl)methyl]oxirane with di-tert-butyl oxalate in hydrazine hydrate. In the crystal, molecules are linked by N—HO and O—HO hydrogen bonds into supramolecular chains propagating along the b-axis direction.
Keywords: crystal structure.