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The title compound, C18H30N2O5S, was synthesized by the reaction of tert-butyl 2-(iso­butyl­amino)­ethyl­carbamate with p-meth­oxy­phenyl­sulfonyl chloride. In the mol­ecule, two intra­molecular C—H...O hydrogen bonds are observed. In the crystal, mol­ecules are linked by N—H...O hydrogen bonds involving the imino group N atom and the ester group O atom into chains running parallel to the b axis. The chains are further connected by C—H...O hydrogen bonds, forming layers parallel to the bc plane.

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The asymmetric unit of the title compound, C8H9N5O2, contains two independent mol­ecules (A and B) in which the dihedral angles between the triazole and pyrazole rings are 4.80 (14) and 8.45 (16)°. In the crystal, mol­ecules are linked by N—H...N hydrogen bonds into supra­molecular independent A and B chains propagating along the b-axis direction. The crystal structure also features π–π stacking between the aromatic rings of adjacent chains, the centroid–centroid separations being 3.8001 (15), 3.8078 (17), 3.8190 (14) and 3.8421 (15) Å.

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The title compound, C14H28N2O5S, was synthesized by the reaction of 2-[(methyl­sulfan­yl)meth­yl]oxirane with di-tert-butyl oxalate in hydrazine hydrate. In the crystal, mol­ecules are linked by N—H...O and O—H...O hydrogen bonds into supra­molecular chains propagating along the b-axis direction.
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