organic compounds
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The asymmetric unit of the title organic–inorganic molecular salt, C6H18N22+·SiF62−, consists of one anion and one cation together with half of each of two cations and two anions located on inversion centres. The SiF62− octahedral anions are arranged to form sheets parallel to (011), which are linked into a three-dimensional network by the organic cations through N—HF hydrogen bonds.