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The title organic-inorganic hybrid compound, {(C7H20N2)[BiCl5]}n, consists of distorted corner-joined [BiCl6] octa­hedra forming zigzag polymeric anionic chains parallel to [001], separated by columns of heptyl­enedi­ammonium cations. The asymmetric unit contains two crystallographically independent bis­muth metal atoms, one of which lies on an inversion centre and the other on a twofold axis. In the crystal, the polymeric chains and cations are linked by N—H...Cl hydrogen bonds, forming undulating layers parallel to (110).
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