metal-organic compounds
Open access
In the title compound, K+·C7H6BrClNO2S−·H2O, the K+ cation is heptacoordinated by two water O atoms, four sulfonyl O atoms of four different N-bromo-4-chloro-2-methylbenzenesulfonamidate anions, and one Br atom of one of the anions. The S—N distance of 1.584 (3) Å is consistent with an S=N double bond. In the crystal, the anions are linked into layers by O—HBr and O—HN hydrogen bonds.
metal-organic compounds
Open access
In the title compound, [K(C7H6Cl2NO2S)(H2O)]n, the K+ cation is heptacoordinated by two water O atoms, a sulfonyl O atom from each of four different N,4-dichloro-2-methylbenzenesulfonamidate anions and a Cl atom of one of the anions. Further, K—O—K bridges form extensive polymeric chains along the b axis. In the crystal structure, the anions are linked into layers parallel to (100) by O—HCl and O—HN hydrogen bonds.